Organic light-emitting diode luminaires

ABSTRACT

There is provided an organic light-emitting diode luminaire. The luminaire includes a patterned first electrode, a second electrode, and a light-emitting layer therebetween. The light-emitting layer includes a first plurality of pixels having an emission color that is blue; a second plurality of pixels having an emission color that is green, the second plurality of pixels being laterally spaced from the first plurality of pixels; and a third plurality of pixels having an emission color that is red-orange, the third plurality of pixels being laterally spaced from the first and second pluralities of pixels. The additive mixing of all the emitted colors results in an overall emission of white light.

RELATED APPLICATION DATA

This application is a divisional of U.S. application Ser. No. 12/861,154filed Aug. 23, 2010 (now granted patent number U.S. Pat. No. 8,476,620),which claims priority under 35 U.S.C. §119(e) from U.S. Application No.61/236,180, filed on Aug. 24, 2009, which are incorporated by referenceherein in their entirety.

BACKGROUND INFORMATION

1. Field of the Disclosure

This disclosure relates in general to organic light-emitting diode(“OLED”) luminaires. It also relates to a process for making suchdevices.

2. Description of the Related Art

Organic electronic devices that emit light are present in many differentkinds of electronic equipment. In all such devices, an organic activelayer is sandwiched between two electrodes. At least one of theelectrodes is light-transmitting so that light can pass through theelectrode. The organic active layer emits light through thelight-transmitting electrode upon application of electricity across theelectrodes. Additional electroactive layers may be present between thelight-emitting layer and the electrode(s).

It is well known to use organic electroluminescent compounds as theactive component in light-emitting diodes. Simple organic molecules,such as anthracene, thiadiazole derivatives, and coumarin derivativesare known to show electroluminescence. In some cases these smallmolecule materials are present as a dopant in a host material to improveprocessing and/or electronic properties.

OLEDs emitting different colors, usually red, green, and blue, can beused in subpixel units to emit white light. OLEDs emitting white lightcan be used for lighting applications.

There is a continuing need for new OLED structures and processes formaking them for lighting applications.

SUMMARY

There is provided an organic light-emitting diode luminaire comprising apatterned first electrode, a second electrode, and a light-emittinglayer therebetween, the light-emitting layer comprising:

-   -   a first plurality of pixels comprising a first        electroluminescent material having an emission color that is        blue;    -   a second plurality of pixels comprising a second        electroluminescent material having an emission color that is        green, the second plurality of pixels being laterally spaced        from the first plurality of pixels; and    -   a third plurality of pixels comprising a third        electroluminescent material having an emission color that is        red-orange, the third plurality of pixels being laterally spaced        from the first and second pluralities of pixels;        wherein the additive mixing of the three emitted colors results        in an overall emission of white light.

There is also provided a process for making an OLED luminaire,comprising:

providing a substrate having a first patterned electrode thereon;

depositing a first liquid composition in a first pixellated pattern toform a first deposited composition, the first liquid compositioncomprising a first electroluminescent material in a first liquid medium,said first electroluminescent material having a first emission color;

depositing a second liquid composition in a second pixellated patternwhich is laterally spaced from the first pixellated pattern to form asecond deposited composition, the second liquid composition comprising asecond electroluminescent material in a second liquid medium, saidsecond electroluminescent material having a second emission color;

depositing a third liquid composition in a third pixellated patternwhich is laterally spaced from the first and second pixellated patternsto form a third deposited composition, the third liquid compositioncomprising a third electroluminescent material in a third liquid medium,said third electroluminescent material having a third emission color;

drying the deposited compositions to form pluralities of pixels; and

forming a second electrode over all the pixels;

wherein one of the emission colors is blue, one of the emission colorsis green, and one of the emission colors is red-orange.

The foregoing general description and the following detailed descriptionare exemplary and explanatory only and are not restrictive of theinvention, as defined in the appended claims.

BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments are illustrated in the accompanying figures to improveunderstanding of concepts as presented herein.

FIG. 1( a) is an illustration of one prior art white light-emittingdevice.

FIG. 1( b) is an illustration of another prior art white light-emittingdevice.

FIG. 2( a) is an illustration of a pixel format for an OLED display.

FIG. 2( b) is an illustration of a pixel format for an OLED luminaire.

FIG. 3 is an illustration of an anode design.

FIG. 4 is an illustration of an OLED luminaire.

Skilled artisans appreciate that objects in the figures are illustratedfor simplicity and clarity and have not necessarily been drawn to scale.For example, the dimensions of some of the objects in the figures may beexaggerated relative to other objects to help to improve understandingof embodiments.

DETAILED DESCRIPTION

Many aspects and embodiments have been described above and are merelyexemplary and not limiting. After reading this specification, skilledartisans appreciate that other aspects and embodiments are possiblewithout departing from the scope of the invention.

Other features and benefits of any one or more of the embodiments willbe apparent from the following detailed description, and from theclaims. The detailed description first addresses Definitions andClarification of Terms followed by the Luminaire, Materials, the Processand finally Examples.

1. DEFINITIONS AND CLARIFICATION OF TERMS

Before addressing details of embodiments described below, some terms aredefined or clarified.

As used herein, the term “alkoxy” refers to the group RO—, where R is analkyl.

The term “alkyl” is intended to mean a group derived from an aliphatichydrocarbon having one point of attachment, and includes a linear, abranched, or a cyclic group. The term is intended to includeheteroalkyls. The term “hydrocarbon alkyl” refers to an alkyl grouphaving no heteroatoms. In some embodiments, an alkyl group has from 1-20carbon atoms.

The term “aryl” is intended to mean a group derived from an aromatichydrocarbon having one point of attachment. The term “aromatic compound”is intended to mean an organic compound comprising at least oneunsaturated cyclic group having delocalized pi electrons. The term isintended include heteroaryls. The term “hydrocarbon aryl” is intended tomean aromatic compounds having no heteroatoms in the ring. In someembodiments, an aryl group has from 3-30 carbon atoms.

The term “blue” refers to an emission with color coordinates ofx=0.12-0.14 and y=0.15-0.21.

The term “color coordinates” refers to the x- and y-coordinatesaccording to the C.I.E. chromaticity scale (Commission Internationale deL'Eclairage, 1931).

The term “CRI” refers to the CIE Color Rendering Index. It is aquantitative measure of the ability of a light source to reproduce thecolors of various objects faithfully in comparison with an ideal ornatural light source. A reference source, such as black body radiation,is defined as having a CRI of 100.

The term “drying” is intended to mean the removal of at least 50% byweight of the liquid medium; in some embodiments, at least 75% by weightof the liquid medium. A “partially dried” layer is one in which someliquid medium remains. A layer which is “essentially completely dried”is one which has been dried to an extent such that further drying doesnot result in any further weight loss.

The term “electroluminescence” refers to the emission of light from amaterial in response to an electric current passed through it.“Electroluminescent” refers to a material that is capable ofelectroluminescence.

The prefix “fluoro” indicates that one or more available hydrogen atomshave been replaced with a fluorine atom.

The term “green” refers to an emission with color coordinates ofx=0.20-0.30 and y=0.55-0.70.

The prefix “hetero” indicates that one or more carbon atoms have beenreplaced with a different atom. In some embodiments, the different atomis N, O, or S.

The term “laterally spaced” refers to spacing within the same plane,where the plane is parallel to the plane of the first electrode.

The term “liquid composition” is intended to mean a liquid medium inwhich a material is dissolved to form a solution, a liquid medium inwhich a material is dispersed to form a dispersion, or a liquid mediumin which a material is suspended to form a suspension or an emulsion.

The term “liquid medium” is intended to mean a liquid material,including a pure liquid, a combination of liquids, a solution, adispersion, a suspension, and an emulsion. Liquid medium is usedregardless whether one or more solvents are present.

The term “luminaire” refers to a lighting panel, and may or may notinclude the associated housing and electrical connections to the powersupply.

The term “overall emission” as it refers to a luminaire, means theperceived light output of the luminaire as a whole.

The term “pitch” as it refers to pixels, means the distance from thecenter of a pixel to the center of the next pixel of the same color.

The term “red-orange” refers to an emission with color coordinates ofx=0.62+/−0.02 and y=0.35+/−0.03.

The term “silyl” refers to the group R₃Si—, where R is H, D, C1-20alkyl, fluoroalkyl, or aryl. In some embodiments, one or more carbons inan R alkyl group are replaced with Si. In some embodiments, the silylgroups are (hexyl)₂Si(CH₃)CH₂CH₂Si(CH₃)₂— and[CF₃(CF₂)₆CH₂CH₂]₂Si(CH₃)—.

The term “white light” refers to light perceived by the human eye ashaving a white color.

All groups may be unsubstituted or substituted. In some embodiments, thesubstituents are selected from the group consisting of D, halide, alkyl,alkoxy, aryl, aryloxy, and fluoroalkyl.

As used herein, the terms “comprises,” “comprising,” “includes,”“including,” “has,” “having” or any other variation thereof, areintended to cover a non-exclusive inclusion. For example, a process,method, article, or apparatus that comprises a list of elements is notnecessarily limited to only those elements but may include otherelements not expressly listed or inherent to such process, method,article, or apparatus. Further, unless expressly stated to the contrary,“or” refers to an inclusive or and not to an exclusive or. For example,a condition A or B is satisfied by any one of the following: A is true(or present) and B is false (or not present), A is false (or notpresent) and B is true (or present), and both A and B are true (orpresent).

Also, use of “a” or “an” are employed to describe elements andcomponents described herein. This is done merely for convenience and togive a general sense of the scope of the invention. This descriptionshould be read to include one or at least one and the singular alsoincludes the plural unless it is obvious that it is meant otherwise.

Group numbers corresponding to columns within the Periodic Table of theelements use the “New Notation” convention as seen in the CRC Handbookof Chemistry and Physics, 81^(st) Edition (2000-2001).

Unless otherwise defined, all technical and scientific terms used hereinhave the same meaning as commonly understood by one of ordinary skill inthe art to which this invention belongs. Although methods and materialssimilar or equivalent to those described herein can be used in thepractice or testing of embodiments of the present invention, suitablemethods and materials are described below. All publications, patentapplications, patents, and other references mentioned herein areincorporated by reference in their entirety, unless a particular passageis cited. In case of conflict, the present specification, includingdefinitions, will control. In addition, the materials, methods, andexamples are illustrative only and not intended to be limiting.

To the extent not described herein, many details regarding specificmaterials, processing acts, and circuits are conventional and may befound in textbooks and other sources within the organic light-emittingdiode display, photodetector, photovoltaic, and semiconductive memberarts.

2. THE LUMINAIRE

It is known to have white light-emitting layers in which emissive layersof different colors are stacked on top of each other between an anodeand a cathode. Two exemplary prior art devices are shown in FIG. 1. InFIG. 1 a, the anode 3 and the cathode 11 have a blue light-emittinglayer 6, a green light-emitting layer 9, and a red light-emitting layer10 stacked between them on substrate 2. On either side of thelight-emitting layers are hole transport layers 4, electron transportlayers 8. there are also hole blocking layers 7 and electron blockinglayers 5. In FIG. 1 b, the substrate 2, anode 3, hole transport layer 4,electron transport layer 8 and cathode 11 are present as shown.Light-emitting layer 12 is a combination of yellow and redlight-emitters in a host material. Light-emitting layer 13 is a bluelight-emitting in a host material. Layer 14 is an additional layer ofhost material.

The luminaire described herein has light emitting layers that arearranged laterally with respect to each other rather than in a stackedconfiguration.

The luminaire has a first patterned electrode, a second electrode, and alight-emitting layer therebetween. The light-emitting layer comprises afirst plurality of pixels having blue emission, a second plurality ofpixels having green emission, and a third plurality of pixels havingred-orange emission. The pluralities of pixels are laterally spaced fromeach other. The additive mixing of the emitted colors results in anoverall emission of white light. At least one of the electrodes is atleast partially transparent to allow for transmission of the generatedlight.

One of the electrodes is an anode, which is an electrode that isparticularly efficient for injecting positive charge carriers. In someembodiments, the first electrode is an anode. In some embodiments, theanode is patterned into parallel stripes. In some embodiments, the anodeis at least partially transparent.

The other electrode is a cathode, which is an electrode that isparticularly efficient for injecting electrons or negative chargecarriers. In some embodiments, the cathode is a continuous, overalllayer. The individual pixels can be of any geometric shape. In someembodiments, they are rectangular or oval.

In some embodiments, the first plurality of pixels is arrayed inparallel stripes of pixels. In some embodiments, the first, second andthird pluralities of pixels are arrayed in alternating parallel stripesof pixels.

The pixel resolution is high enough so that the first, second and thirdcolors are not seen individually, and the overall emission is of whitelight. In some embodiments, the pitch between pixels of the same coloris no greater than 200 microns. In some embodiments. the pitch is nogreater than 150 microns. In some embodiments, the pitch is no greaterthan 100 microns.

The electroluminescent materials can be chosen based on high luminousefficiency instead, as long as high CRI values are obtainable.

In some embodiments, the pixels of each color have different sizes. Thiscan be done in order to obtain the best mix of color to achieve whitelight emission. In the embodiments with parallel stripes of pixels, thewidth of the pixels can be different. The widths are chosen to allow thecorrect color balance while each color is operating at the sameoperating voltage. An illustration of this is given in FIG. 2. FIG. 2(a) shows the typical layout of an OLED display 100, with pixels 110,120, and 130 having equal width. This layout may also be used for theluminaire described herein. FIG. 2( b) shows another embodiment of thelayout for an OLED luminaire 200, with pixels 210, 220, and 230, whichhave different widths. The pixel pitch is shown as “p”.

The OLED device also includes bus lines for delivering power to thedevice. In some embodiments, some of the bus lines are present in theactive area of the device, spaced between the lines of pixels. The buslines may be present between every x number of pixel lines, where x isan integer and the value is determined by the size and electronicrequirements of the luminaire. In some embodiments, the bus lines arepresent every 10-20 pixel lines. In some embodiments, the metal buslines are ganged together to give only one electrical contact for eachcolor.

The ganging together of the electrodes allows for simple driveelectronics and consequently keeps fabrication costs to a minimum. Apotential problem that could arise with such a design is that thedevelopment of an electrical short in any of the pixels could lead to ashort-circuit of the whole luminaire and a catastrophic failure. In someembodiments, this can be addressed by designing the pixels to haveindividual “weak links”. As a result, a short in any one pixel will onlycause a failure of that pixel—the rest of the luminaire will continue tofunction with an unnoticed reduction in light output. One possible anodedesign is shown in FIG. 3. The anode 250 is connected to the metal busline 260 by a narrow stub 270. The stub 270 is sufficient to carry thecurrent during operation but will fail if the pixel should shortcircuit, thereby isolating the short to a single pixel.

In some embodiments, the OLED luminaire includes bank structures todefine the pixel openings. The term “bank structure” is intended to meana structure overlying a substrate, wherein the structure serves aprincipal function of separating an object, a region, or any combinationthereof within or overlying the substrate from contacting a differentobject or different region within or overlying the substrate.

In some embodiments, the OLED luminaire further comprises additionallayers. In some embodiments, the OLED luminaire further comprises one ormore charge transport layers. The term “charge transport,” whenreferring to a layer, material, member, or structure is intended to meansuch layer, material, member, or structure facilitates migration of suchcharge through the thickness of such layer, material, member, orstructure with relative efficiency and small loss of charge. Holetransport layers facilitate the movement of positive charges; electrontransport layers facilitate the movements of negative charges. Althoughelectroluminescent materials may also have some charge transportproperties, the term “charge transport layer, material, member, orstructure” is not intended to include a layer, material, member, orstructure whose primary function is light emission.

In some embodiments, the OLED luminaire further comprises one or morehole transport layers between the electroluminescent layer and theanode. In some embodiments, the OLED luminaire further comprises one ormore electron transport layers between the electroluminescent layer andthe cathode.

In some embodiments, the OLED luminaire further comprises a holeinjection layer between the anode and a hole transport layer. The term“hole injection layer” or “hole injection material” is intended to meanelectrically conductive or semiconductive materials. The hole injectionlayer may have one or more functions in an organic electronic device,including but not limited to, planarization of the underlying layer,charge transport and/or charge injection properties, scavenging ofimpurities such as oxygen or metal ions, and other aspects to facilitateor to improve the performance of the organic electronic device.

One example of an OLED luminaire is illustrated in FIG. 4. OLEDluminaire 300 has substrate 310 with anode 320 and bus lines 330. Bankstructures 340 contain the organic layers: hole injection layer 350,hole transport layer 360, and the electroluminescent layers 371, 372,and 373, for colors red-orange, green, and blue, respectively. Theelectron transport layer 380 and cathode 390 are applied overall.

The OLED luminaire can additionally be encapsulated to preventdeterioration due to air and/or moisture. Various encapsulationtechniques are known. In some embodiments, encapsulation of large areasubstrates is accomplished using a thin, moisture impermeable glass lid,incorporating a desiccating seal to eliminate moisture penetration fromthe edges of the package. Encapsulation techniques have been describedin, for example, published US application 2006-0283546.

There can be different variations of OLED luminaires which differ onlyin the complexity of the drive electronics (the OLED panel itself is thesame in all cases). The drive electronics designs can still be verysimple.

In one embodiment, unequal pixel widths are chosen so that the desiredwhite point is achieved with all three colors operating at the samevoltage (around 5-6V). All three colors are ganged together. Therequired drive electronics is thus a simple stabilized DC voltagesupply.

In one embodiment, unequal pixel widths are chosen and the three colorsare driven by three separate DC supplies, thereby allowing each color tobe adjusted independently. This gives the possibility of a userselectable white point (e.g. to simulate sunlight, incandescent lamps orfluorescent lighting). This also allows for the adjustment of the colorpoint if the color should drift as the luminaire ages. This designrequires three DC voltage supplies. It is also possible that theluminaire could be programmed to cycle through a range of colors. Thishas potentially interesting application in commercial advertising orstore displays.

In some embodiments, accurate white point color is required and colordrift with ageing is not acceptable. In this case, unequal pixel widthsare chosen and the three colors are driven by three separate DCsupplies. In addition, the luminaire includes an external color sensorallowing the colors to be automatically adjusted to maintain the whitepoint color.

3. MATERIALS

a. Electroluminescent Layer

Any type of electroluminescent (“EL”) material can be used in theelectroluminescent layer, including, but not limited to, small moleculeorganic luminescent compounds, luminescent metal complexes, conjugatedpolymers, and mixtures thereof. Examples of luminescent compoundsinclude, but are not limited to, pyrene, perylene, rubrene, coumarin,derivatives thereof, and mixtures thereof. Examples of metal complexesinclude, but are not limited to, metal chelated oxinoid compounds, suchas tris(8-hydroxyquinolato)aluminum (Alq3); cyclometalated iridium andplatinum electroluminescent compounds, such as complexes of iridium withphenylpyridine, phenylquinoline, or phenylpyrimidine ligands asdisclosed in Petrov et al., U.S. Pat. No. 6,670,645 and Published PCTApplications WO 03/063555 and WO 2004/016710, and organometalliccomplexes described in, for example, Published PCT Applications WO03/008424, WO 03/091688, and WO 03/040257, and mixtures thereof.Electroluminescent emissive layers comprising a charge carrying hostmaterial and a metal complex have been described by Thompson et al., inU.S. Pat. No. 6,303,238, and by Burrows and Thompson in published PCTapplications WO 00/70655 and WO 01/41512. Examples of conjugatedpolymers include, but are not limited to poly(phenylenevinylenes),polyfluorenes, poly(spirobifluorenes), polythiophenes,poly(p-phenylenes), copolymers thereof, and mixtures thereof.

In some embodiments, the first electroluminescent material with blueemission color is an organometallic complex of Ir. In some embodiments,the organometallic Ir complex is a tris-cyclometallated complex havingthe formula IrL₃ or a bis-cyclometallated complex having the formulaIrL₂Y, where Y is a monoanionic bidentate ligand and L has a formulaselected from the group consisting of Formula L-1 through Formula L-12:

where R¹ through R⁸ are the same or different and are selected from thegroup consisting of H, D, electron-donating groups, andelectron-withdrawing groups, and R⁹ is H, D or alkyl.

The emitted color is tuned by the selection and combination ofelectron-donating and electron-withdrawing substituents. In addition,the color is tuned by the choice of Y ligand in the bis-cyclometallatedcomplexes. Shifting the color to shorter wavelengths is accomplished by(a) selecting one or more electron-donating substituents for R¹ throughR⁴; and/or (b) selecting one or more electron-withdrawing substituentsfor R⁵ through R⁸; and/or (c) selecting a bis-cyclometallated complexwith ligand Y-1, shown below. Conversely, shifting the color to longerwavelengths is accomplished by (a) selecting one or moreelectron-withdrawing substituents for R¹ through R⁴; and/or (b)selecting one or more electron-donating substituents for R⁵ through R⁸;and/or (c) selecting a bis-cyclometallated complex with ligand Y-2,shown below. Examples of electron-donating substituents include, but arenot limited to, alkyl, silyl, alkoxy, and dialkylamino. Examples ofelectron-withdrawing substituents include, but are not limited to, F,CN, fluoroalkyl, and fluoroalkoxy. Substituents may also be chosen toaffect other properties of the materials, such as solubility, air andmoisture stability, emissive lifetime, and others.

In some embodiments of Formulae L-1 through L-12, at least one of R¹through R⁴ is an electron-donating substituent. In some embodiments ofFormula L-1, at least one of R⁵ through R⁸ is an electron-withdrawingsubstituent.

In some embodiments of Formulae L-1 through L-12:

-   -   R¹ is H, D, F, or alkyl;    -   R² is H, D or alkyl;    -   R³═H, D, F, alkyl, OR¹⁰, NR¹⁰ ₂;    -   R⁴═H or D    -   R⁵═FI, D or F;    -   R⁶═H, D, F, CN, aryl, fluoroalkyl, or diaryloxophosphinyl;    -   R⁷═H, D, F, alkyl, aryl, or diaryloxophosphinyl;    -   R⁸═H, D, CN, alkyl, fluoroalkyl;    -   R⁹═H, D, alkyl; aryl;    -   R¹⁰=alkyl, where adjacent R¹⁰ groups can be joined to form a        saturated ring; and    -   * represents a point of coordination with Ir.

In some embodiments, Y is selected from the group consisting of Y-1, Y-2and Y-3

wherein:

-   -   R¹¹ is the same or different at each occurrence and is selected        from the group consisting of alkyl and fluoroalkyl;    -   R¹² is H, D or F; and    -   R¹³ is the same or different at each occurrence and is selected        from the group consisting of alkyl and fluoroalkyl.

In some embodiments, the alkyl and fluoroalkyl groups have 1-5 carbonatoms. In some embodiments, the alkyl group is methyl. In someembodiments, the fluoroalkyl group is trifluoromethyl. In someembodiments, the aryl group is a heteroaryl. In some embodiments, thearyl group is a phenyl group having one or more substituents selectedfrom the group consisting of F, CN, and CF₃. In some embodiments, thearyl group is selected from the group consisting of o-fluorophenyl,m-fluorophenyl, p-fluorophenyl, p-cyanophenyl, and3,5-bis(trifluoromethyl)phenyl. In some embodiments, thediaryloxophosphinyl group is diphenyloxophosphinyl.

In some embodiments, the organometallic Ir complex having blue emissioncolor has the formula IrL₃. In some embodiments, the complex has theformula IrL₃, where L is Formula L-1, R⁵ is H, D and R⁶ is F, aryl,heteroaryl, or diaryloxophosphinyl. In some embodiments, R⁵ is F and R⁶is H or D. In some embodiments, two or more of R⁵, R⁶, R⁷ and R⁸ are F.

In some embodiments, the organometallic Ir complex having blue emissioncolor has the formula IrL₂Y. In some embodiments, the complex has theformula IrL₂Y, where L is Formula L-1, R¹, R², R⁶ and R⁸ are H or D. Insome embodiments, R⁵ and R⁷ are F.

Examples of organometallic Ir complexes having blue emission colorinclude, but are not limited to:

In some embodiments, the first electroluminescent material with blueemission color is a small molecule luminescent organic compound. In someembodiments, the luminescent organic compound is a chrysene derivativehaving Formula I

wherein:

-   -   R¹⁴, R¹⁶, R¹⁶ and R¹⁷ are the same or different and are selected        from the group consisting of H, D, and alkyl, where R¹⁴ and R¹⁵        groups or R¹⁶ and R¹⁷ groups may be joined together to form a 5-        or 6-membered aliphatic ring;    -   R¹⁸ and R¹⁹ are the same or different and are selected from the        group consisting of D, alkyl groups, silyl groups, m-phenyl,        o-phenyl, p-phenyl, m-N-carbazolyl, and p-N-carbazolyl;    -   R²⁰ is the same or different at each occurrence and is selected        from the group consisting of D, alkyl groups, silyl groups,        phenyl, and biphenyl, or two adjacent R²⁰ groups can join        together to form a naphthyl or fluorenyl group;    -   a and b are the same or different and are an integer from 0-10;    -   c and d are the same or different and are an integer from 1-5;    -   f, g, h, and i, are the same or different at each occurrence and        are an integer from 0-4; and    -   e and j are the same or different at each occurrence and are an        integer from 0-5.

Examples of chrysene compounds with blue emission color include, but arenot limited to:

In some embodiments, the second electroluminescent material with greenemission color is an organometallic complex of Ir. In some embodiments,the organometallic Ir complex is a tris-cyclometallated complex havingthe formula IrL₃ or a bis-cyclometallated complex having the formulaIrL₂Y, where Y is a monoanionic bidentate ligand and L has a formulaselected from the group consisting of L-1, L-3 through L-7, and L-9through L-17:

where R¹ through R⁸ are the same or different and are selected from thegroup consisting of H, D, electron-donating groups, andelectron-withdrawing groups, and R⁹ is H, D or alkyl.

As discussed above, the emitted color is tuned by the selection andcombination of electron-donating and electron-withdrawing substituentsand the selection of the Y ligand.

In some embodiments, of Formulae L-1, L-3 through L-7, and L-9 throughL-17:

-   -   R¹═H, D or F;    -   R²═H, D, F, or alkyl;    -   R³═H, D or diarylamino;    -   R⁴═H, D or F;    -   R⁵═H, D or alkyl, or R⁴ and R⁵ may be joined together to form a        6-membered aromatic ring;    -   R⁶═H, D, F, aryl, fluoroalkoxy, N-carbazolyl,        diphenyl-N-carbazolyl, or

-   -   R⁷═H, D, F, fluoroalkoxy, N-carbazolyl, or        diphenyl-N-carbazolyl;    -   R⁸═H, D or F; and    -   R⁹═H, D, aryl or alkyl,    -   where the asterisk represents the point of attachment.

In some embodiments, Y is selected from the group consisting of Y-1, Y-2and Y-3

wherein:

-   -   R¹¹ is the same or different at each occurrence and is selected        from the group consisting of alkyl and fluoroalkyl;    -   R¹² is H, D or F; and    -   R¹³ is the same or different at each occurrence and is selected        from the group consisting of alkyl and fluoroalkyl.

In some embodiments, the alkyl and fluoroalkyl groups have 1-5 carbonatoms. In some embodiments, the alkyl group is methyl. In someembodiments, the fluoroalkyl group is trifluoromethyl. In someembodiments, the aryl group is a heteroaryl. In some embodiments, thearyl group is N-carbazolyl or diphenyl-N-carbazolyl. In someembodiments, the aryl group is phenyl or substituted phenyl. In someembodiments, the aryl group is a phenyl group having one or moresubstituents selected from the group consisting of F, CN, alkyl, andfluoroalkyl. In some embodiments, the aryl group is selected from thegroup consisting of p-(C₁₋₅)alkylphenyl, o-fluorophenyl, m-fluorophenyl,p-fluorophenyl, p-cyanophenyl, and 3,5-bis(trifluoromethyl)phenyl.

In some embodiments, the organometallic Ir complex having green emissioncolor has the formula IrL₃ where L has Formula L-1. In some embodimentsof Formula L-1, R² is H, D, or methyl and R¹, R³ and R⁴ are H or D. Insome embodiments, R⁶ is selected from the group consisting of phenyl,substituted phenyl, N-carbazolyl, and diphenyl-N-carbazolyl.

Examples of organometallic Ir complexes with green emission colorinclude, but are not limited to

In some embodiments, the third electroluminescent material withred-orange emission color is an organometallic complex of Ir. In someembodiments, the organometallic Ir complex is a tris-cyclometallatedcomplex having the formula IrL₃ or a bis-cyclometallated complex havingthe formula IrL₂Y, where Y is a monoanionic bidentate ligand and L has aformula selected from the group consisting of Formula L-18, L-19, L-20and L-21:

where:

-   -   R¹ through R⁶ and R²¹ through R³⁰ are the same or different and        are selected from the group consisting of H, D,        electron-donating groups, and electron-withdrawing groups; and    -   * represents a point of coordination with Ir.

As discussed above, the emitted color is tuned by the selection andcombination of electron-donating and electron-withdrawing substituents,and by the selection of the Y ligand in the bis-cyclometallatedcomplexes. Shifting the color to shorter wavelengths is accomplished by(a) selecting one or more electron-donating substituents for R¹ throughR⁴ or R²¹ through R²⁶; and/or (b) selecting one or moreelectron-withdrawing substituents for R⁵ through R⁶ or R²⁷ through R³⁰;and/or (c) selecting a bis-cyclometallated complex with ligand Y-2 orY-3. Conversely, shifting the color to longer wavelengths isaccomplished by (a) selecting one or more electron-withdrawingsubstituents for R¹ through R⁴ or R²¹ through R²⁶; and/or (b) selectingone or more electron-donating substituents for R⁵ through R⁶ or R²⁷through R³⁰; and/or (c) selecting a bis-cyclometallated complex withligand Y-1.

In some embodiments of Formulae L-18 through L-21:

-   -   R¹ through R⁴ and R²¹ through R²⁶ are the same or different and        are H, D, alkyl, silyl, or alkoxy, or R¹ and R², R² and R³ or R³        and R⁴ in ligand L-18, or R²³ and R²⁴ or R²⁴ and R²⁵ in ligand        L-19 and L-20, or R²³ and R²⁴, R²⁴ and R²⁵, or R²⁵ and R²⁶ in        Ligand L-21 can be joined together to form a hydrocarbon ring or        hetero ring;    -   R²⁷═H, D, alkyl, or silyl;    -   R²⁸═H, D, alkyl, or silyl;    -   R²⁹═H, D, alkyl, silyl, alkoxy, fluoroalkoxy, or aryl; and    -   R³⁰═H, D, alkyl, or silyl.

In some embodiments, Y is selected from the group consisting of Y-1, Y-2and Y-3

wherein:

-   -   R¹¹ is the same or different at each occurrence and is selected        from the group consisting of alkyl and fluoroalkyl;    -   R¹² is H, D or F; and    -   R¹³ is the same or different at each occurrence and is selected        from the group consisting of alkyl and fluoroalkyl.

In some embodiments of the formulae, the alkyl, fluoroalkyl, alkoxy andfluoroalkoxy groups have 1-5 carbon atoms. In some embodiments, thealkyl group is methyl. In some embodiments, the alkoxy group is methoxy.In some embodiments, the fluoroalkyl group is trifluoromethyl. In someembodiments, the aryl group is phenyl.

In some embodiments, L=L-19 and the complex has the formula IrL₃. Insome embodiments, L=L-20 and the complex has the formula IrL₂Y or IrL₃.In some embodiments, L=L-19 and the complex has the formula IrL₂Y.

In some embodiments of L-19, at least one of R²³ through R²⁶ is alkoxy.In some embodiments of L-19, at least one of R²⁷ through R³⁰ is alkoxyor fluoroalkoxy.

In some embodiments, L=L-20 R²³ through R²⁶ are H or D. In someembodiments of L-20, at least one of R²¹ and R²⁹ is a C₁₋₅ alkyl group.

In some embodiments of L-21, R²³ through R²⁶ are H or D. In someembodiments of L-21, at least one of R²¹ and R²⁹ is a C₁₋₅ alkyl group.In some embodiments of L-21, at least one of R²⁷ through R³⁰ is a C₁₋₅alkoxy or fluoroalkoxy group.

Examples of organometallic Ir complexes having red-orange emission colorinclude, but are not limited to:

In some embodiments, the electroluminescent materials are present as adopant in a host material. The term “host material” is intended to meana material, usually in the form of a layer, to which anelectroluminescent material may be added. The host material may or maynot have electronic characteristic(s) or the ability to emit, receive,or filter radiation. Host materials have been disclosed in, for example,U.S. Pat. No. 7,362,796, and published US patent application2006-0115676.

In some embodiments, the host is an anthracene derivative compound. Insome embodiments the compound has the formula:An-L-Anwhere:

-   -   An is an anthracene moiety;    -   L is a divalent connecting group.        In some embodiments of this formula, L is a single bond, —O—,        —S—, —N(R)—, or an aromatic group. In some embodiments, An is a        mono- or diphenylanthryl moiety.

In some embodiments, the host has the formula:A-An-Awhere:

-   -   An is an anthracene moiety;    -   A is the same or different at each occurrence and is an aromatic        group.

In some embodiments, the A groups are attached at the 9- and10-positions of the anthracene moiety. In some embodiments, A isselected from the group consisting naphthyl, naphthylphenylene, andnaphthylnaphthylene. In some embodiments the compound is symmetrical andin some embodiments the compound is non-symmetrical.

In some embodiments, the host has the formula:

where:

A¹ and A² are the same or different at each occurrence and are selectedfrom the group consisting of H, D, an aromatic group, an alkyl group andan alkenyl group, or A may represent one or more fused aromatic rings;

p and q are the same or different and are an integer from 1-3. In someembodiments, the anthracene derivative is non-symmetrical. In someembodiments, p=2 and q=1.

In some embodiments, at least one of A¹ and A² is a naphthyl group. Insome embodiments, additional substituents are present.

In some embodiments, the host material has the formula

where:

-   -   Ar¹ to Ar⁴ are the same or different and are aryl;    -   Q is selected from the group consisting of multivalent aryl        groups and

-   -   T is selected from the group consisting of (CR′)_(a), SiR₂, S,        SO₂, PR, PO, PO₂, BR, and R;    -   R is the same or different at each occurrence and is selected        from the group consisting of alkyl, and aryl;    -   R′ is the same or different at each occurrence and is selected        from the group consisting of H, D, and alkyl;    -   a is an integer from 1-6; and    -   m is an integer from 0-6.

In some embodiments of Formula I, adjacent Ar groups are joined togetherto form rings such as carbazole. In Formula I, “adjacent” means that theAr groups are bonded to the same N.

In some embodiments, Ar¹ to Ar⁴ are independently selected from thegroup consisting of phenyl, biphenyl, terphenyl, quaterphenyl, naphthyl,phenanthryl, naphthylphenyl, and phenanthrylphenyl. Analogs higher thanquaterphenyl can also be used, having 5-10 phenyl rings.

In some embodiments, Q is an aryl group having at least two fused rings.In some embodiments, Q has 3-5 fused aromatic rings. In someembodiments, Q is selected from the group consisting of chrysene,phenanthrene, triphenylene, phenanthroline, naphthalene, anthracene,quinoline and isoquinoline.

In some embodiments, the host material is an electron transportmaterial. In some embodiments, the host material is selected from thegroup consisting of phenanthrolines, quinoxalines, phenylpyridines,benzodifurans, and metal quinolinate complexes.

In some embodiments, the host material is a phenanthroline derivativehaving the formula

where:

-   -   R³¹ is the same or different and is selected from the group        consisting of phenyl, naphthyl, naphthylphenyl, triphenylamino,        and carbazolylphenyl;    -   R³² and R³³ are the same or different and are selected from the        group consisting of phenyl, biphenyl, naphthyl, naphthylphenyl,        phenanthryl, triphenylamino, and carbazolylphenyl.

In some embodiments of the phenanthroline derivative, both R³¹ arephenyl and R³² and R³³ are selected from the group consisting of phenyl,2-naphthyl, naphthylphenyl, phenanthryl, triphenylamino, andm-carbazolylphenyl.

Some examples of host materials include, but are not limited to:

The amount of dopant present in the electroluminescent composition isgenerally in the range of 3-20% by weight, based on the total weight ofthe composition; in some embodiments, 5-15% by weight. In someembodiments, a combination of two hosts is present.

The overall emission of white light can be achieved by balancing theemission of the three colors. In some embodiments, when the firstelectroluminescent material having blue emission is an organometalliciridium complex, the relative emission from the three colors, asmeasured in cd/m², is as follows:

blue emission=28-33%,

green emission=32-37%, and

red-orange emission=31-36%.

In some embodiments, when the first electroluminescent material havingblue emission is a small molecule luminescent organic compound, therelative emission from the three colors, as measured in cd/m², is asfollows:

blue emission=20-25%,

green emission=47-52%, and

red-orange emission=27-32%.

b. Other Layers

The materials to be used for the other layers of the luminaire describedherein can be any of those known to be useful in OLED devices.

The anode is an electrode that is particularly efficient for injectingpositive charge carriers. It can be made of, for example materialscontaining a metal, mixed metal, alloy, metal oxide or mixed-metaloxide, or it can be a conducting polymer, and mixtures thereof. Suitablemetals include the Group 11 metals, the metals in Groups 4, 5, and 6,and the Group 8-10 transition metals. If the anode is to belight-transmitting, mixed-metal oxides of Groups 12, 13 and 14 metals,such as indium-tin-oxide, are generally used. The anode may alsocomprise an organic material such as polyaniline as described in“Flexible light-emitting diodes made from soluble conducting polymer,”Nature vol. 357, pp 477 479 (11 Jun. 1992). At least one of the anodeand cathode should be at least partially transparent to allow thegenerated light to be observed.

The hole injection layer comprises hole injection materials. Holeinjection materials may be polymers, oligomers, or small molecules, andmay be in the form of solutions, dispersions, suspensions, emulsions,colloidal mixtures, or other compositions.

The hole injection layer can be formed with polymeric materials, such aspolyaniline (PANI) or polyethylenedioxythiophene (PEDOT), which areoften doped with protonic acids. The protonic acids can be, for example,poly(styrenesulfonic acid), poly(2-acrylamido-2-methyl-1-propanesulfonicacid), and the like. The hole injection layer can comprise chargetransfer compounds, and the like, such as copper phthalocyanine and thetetrathiafulvalene-tetracyanoquinodimethane system (TTF-TCNQ). In oneembodiment, the hole injection layer is made from a dispersion of aconducting polymer and a colloid-forming polymeric acid. Such materialshave been described in, for example, published U.S. patent applications2004-0102577, 2004-0127637, and 2005-0205860, and published PCTapplication WO 2009/018009.

The hole transport layer comprises hole transport material. Examples ofhole transport materials for the hole transport layer have beensummarized for example, in Kirk-Othmer Encyclopedia of ChemicalTechnology, Fourth Edition, Vol. 18, p. 837-860, 1996, by Y. Wang. Bothhole transporting small molecules and polymers can be used. Commonlyused hole transporting molecules include, but are not limited to:4,4′,4″-tris(N,N-diphenyl-amino)-triphenylamine (TDATA);4,4′,4″-tris(N-3-methylphenyl-N-phenyl-amino)-triphenylamine (MTDATA);N,N′-diphenyl-N,N′-bis(3-methylphenyl)-[1,1′-biphenyl]-4,4′-diamine(TPD); 4,4′-bis(carbazol-9-yl)biphenyl (CBP);1,3-bis(carbazol-9-yl)benzene (mCP); 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC);N,N′-bis(4-methylphenyl)-N,N′-bis(4-ethylphenyl)-[1,1′-(3,3′-dimethyl)biphenyl]-4,4′-diamine(ETPD); tetrakis-(3-methylphenyl)-N,N,N′,N′-2,5-phenylenediamine (PDA);α-phenyl-4-N,N-diphenylaminostyrene (TPS); p-(diethylamino)benzaldehydediphenylhydrazone (DEH); triphenylamine (TPA);bis[4-(N,N-diethylamino)-2-methylphenyl](4-methylphenyl)methane (MPMP);1-phenyl-3-[p-(diethylamino)styryl]-5-[p-(diethylamino)phenyl]pyrazoline(PPR or DEASP); 1,2-trans-bis(9H-carbazol-9-yl)cyclobutane (DCZB);N,N,N′,N′-tetrakis(4-methylphenyl)-(1,1′-biphenyl)-4,4′-diamine (TTB);N,N′-bis(naphthalen-1-yl)-N,N′-bis-(phenyl)benzidine (α-NPB); andporphyrinic compounds, such as copper phthalocyanine. Commonly used holetransporting polymers include, but are not limited to,polyvinylcarbazole, (phenylmethyl)polysilane, poly(dioxythiophenes),polyanilines, and polypyrroles. It is also possible to obtain holetransporting polymers by doping hole transporting molecules such asthose mentioned above into polymers such as polystyrene andpolycarbonate. In some cases, triarylamine polymers are used, especiallytriarylamine-fluorene copolymers. In some cases, the polymers andcopolymers are crosslinkable. Examples of crosslinkable hole transportpolymers can be found in, for example, published US patent application2005-0184287 and published PCT application WO 2005/052027. In someembodiments, the hole transport layer is doped with a p-dopant, such astetrafluorotetracyanoquinodimethane andperylene-3,4,9,10-tetracarboxylic-3,4,9,10-dianhydride.

The electron transport layer can function both to facilitate electrontransport, and also serve as a buffer layer or confinement layer toprevent quenching of the exciton at layer interfaces. Preferably, thislayer promotes electron mobility and reduces exciton quenching. Examplesof electron transport materials which can be used in the optionalelectron transport layer, include metal chelated oxinoid compounds,including metal quinolate derivatives such astris(8-hydroxyquinolato)aluminum (AlQ),bis(2-methyl-8-quinolinolato)(p-phenylphenolato) aluminum (BAIq),tetrakis-(8-hydroxyquinolato)hafnium (HfQ) andtetrakis-(8-hydroxyquinolato)zirconium (ZrQ); and azole compounds suchas 2-(4-biphenylyl)-5-(4-t-butylphenyl)-1,3,4-oxadiazole (PBD),3-(4-biphenylyl)-4-phenyl-5-(4-t-butylphenyl)-1,2,4-triazole (TAZ), and1,3,5-tri(phenyl-2-benzimidazole)benzene (TPBI); quinoxaline derivativessuch as 2,3-bis(4-fluorophenyl)quinoxaline; phenanthrolines such as4,7-diphenyl-1,10-phenanthroline (DPA) and2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (DDPA); and mixturesthereof. In some embodiments, the electron transport layer furthercomprises an n-dopant. N-dopant materials are well known. The n-dopantsinclude, but are not limited to, Group 1 and 2 metals; Group 1 and 2metal salts, such as LiF, CsF, and Cs₂CO₃; Group 1 and 2 metal organiccompounds, such as Li quinolate; and molecular n-dopants, such as leucodyes, metal complexes, such as W₂(hpp)₄ wherehpp=1,3,4,6,7,8-hexahydro-2H-pyrimido-[1,2-a]-pyrimidine andcobaltocene, tetrathianaphthacene,bis(ethylenedithio)tetrathiafulvalene, heterocyclic radicals ordiradicals, and the dimers, oligomers, polymers, dispiro compounds andpolycycles of heterocyclic radical or diradicals.

The cathode, is an electrode that is particularly efficient forinjecting electrons or negative charge carriers. The cathode can be anymetal or nonmetal having a lower work function than the anode. Materialsfor the cathode can be selected from alkali metals of Group 1 (e.g., Li,Cs), the Group 2 (alkaline earth) metals, the Group 12 metals, includingthe rare earth elements and lanthanides, and the actinides. Materialssuch as aluminum, indium, calcium, barium, samarium and magnesium, aswell as combinations, can be used. Li-containing organometalliccompounds, LiF, Li₂O, Cs-containing organometallic compounds, CsF, Cs₂O,and Cs₂CO₃ can also be deposited between the organic layer and thecathode layer to lower the operating voltage. This layer may be referredto as an electron injection layer.

The choice of materials for each of the component layers is preferablydetermined by balancing the positive and negative charges in the emitterlayer to provide a device with high electroluminescence efficiency.

In one embodiment, the different layers have the following range ofthicknesses: anode, 500-5000 Å, in one embodiment 1000-2000 Å; holeinjection layer, 50-2000 Å, in one embodiment 200-1000 Å; hole transportlayer, 50-2000 Å, in one embodiment 200-1000 Å; photoactive layer,10-2000 Å, in one embodiment 100-1000 Å; electron transport layer,50-2000 Å, in one embodiment 100-1000 Å; cathode, 200-10000 Å, in oneembodiment 300-5000 Å. The desired ratio of layer thicknesses willdepend on the exact nature of the materials used.

The OLED luminaire may also include outcoupling enhancements to increaseoutcoupling efficiency and prevent waveguiding on the side of thedevice. Types of light outcoupling enhancements include surface films onthe viewing side which include ordered structures like e.g. microspheres or lenses. Another approach is the use of random structures toachieve light scattering like sanding of the surface and or theapplication of an aerogel.

The OLED luminaires described herein can have several advantages overincumbent lighting materials. The OLED luminaires have the potential forlower power consumption than incandescent bulbs. Efficiencies of greaterthan 50 Im/W may be achieved. The OLED luminaires can have Improvedlight quality vs. fluorescent. The color rendering can be greater than80, vs that of 62 for fluorescent bulbs. The diffuse nature of the OLEDreduces the need for an external diffuser unlike all other lightingoptions. With simple electronics, the brightness and the color can betunable by the user, unlike other lighting options.

In addition, the OLED luminaires described herein have advantages overother white light-emitting devices. The structure is much simpler thandevices with stacked electroluminescent layers. It is easier to tune thecolor. There is higher material utilization than with devices formed byevaporation of electroluminescent materials. It is possible to use anytype of electroluminescent material.

4. PROCESS

The process for making an OLED luminaire, comprises:

providing a substrate having a first patterned electrode thereon;

depositing a first liquid composition in a first pixellated pattern toform a first deposited composition, the first liquid compositioncomprising a first electroluminescent material in a first liquid medium,said first electroluminescent material having a first emission color;

depositing a second liquid composition in a second pixellated patternwhich is laterally spaced from the first pixellated pattern to form asecond deposited composition, the second liquid composition comprising asecond electroluminescent material in a second liquid medium, saidsecond electroluminescent material having a second emission color;

depositing a third liquid composition in a third pixellated patternwhich is laterally spaced from the first and second pixellated patternsto form a third deposited composition, the third liquid compositioncomprising a third electroluminescent material in a third liquid medium,said third electroluminescent material having a third emission color;

drying the deposited compositions to form pluralities of pixels; and

forming a second electrode over all the pixels;

wherein one of the emission colors is blue, one of the emission colorsis green, and one of the emission colors is red-orange.

Any known liquid deposition technique can be used, including continuousand discontinuous techniques. Examples of continuous liquid depositiontechniques include, but are not limited to spin coating, gravurecoating, curtain coating, dip coating, slot-die coating, spray coating,and continuous nozzle coating. Examples of discontinuous depositiontechniques include, but are not limited to, ink jet printing, gravureprinting, and screen printing.

The drying step can take place after the deposition of each color, afterthe deposition of all the colors, or any combination thereof. Anyconventional drying technique can be used, including heating, vacuum,and combinations thereof. In some embodiments, the drying steps resultin a layer that is partially dried. In some embodiments, the dryingsteps together result in a layer that is essentially completely dried.Further drying of the essentially completely dried layer does not resultin any further device performance changes.

In some embodiments, the drying step is carried out after deposition ofall the colors. In some embodiments, the drying step is a multi-stageprocess. In some embodiments, the drying step has a first stage in whichthe deposited compositions are partially dried and a second stage inwhich the partially dried compositions are essentially completely dried.

The drying steps can take place after the deposition of each color,after the deposition of all the colors, or any combination thereof. Anyconventional drying technique can be used, including heating, vacuum,and combinations thereof.

In some embodiments, the process further comprises deposition of achemical containment layer. The term “chemical containment layer” isintended to mean a patterned layer that contains or restrains the spreadof a liquid material by surface energy effects rather than physicalbarrier structures. The term “contained” when referring to a layer, isintended to mean that the layer does not spread significantly beyond thearea where it is deposited. The term “surface energy” is the energyrequired to create a unit area of a surface from a material. Acharacteristic of surface energy is that liquid materials with a givensurface energy will not wet surfaces with a lower surface energy.

In some embodiments, the process uses as a substrate a glass substratewith patterned ITO and metal bus lines. The substrate may also containbank structures to define the individual pixels. The bank structures canbe formed and patterned using any conventional technique, such asstandard photolithography techniques. Slot-die coating can be used tocoat a buffer layer from aqueous solution, followed by a second passthrough a slot-die coater for a hole transport layer. These layers arecommon to all pixels and consequently are not patterned. Thelight-emitting layers can be patterned using nozzle-printing equipment.In some embodiments, pixels are printed in columns with lateraldimensions of about 40 microns. Both the slot-die process steps and thenozzle-printing can be carried out in a standard clean-room atmosphere.Next the device is transported to a vacuum chamber for the deposition ofthe electron transport layer and the metallic cathode. This is the onlystep that requires vacuum chamber equipment. Finally, the wholeluminaire is hermetically sealed using encapsulation technology, asdescribed above.

Note that not all of the activities described above in the generaldescription are required, that a portion of a specific activity may notbe required, and that one or more further activities may be performed inaddition to those described. Still further, the order in whichactivities are listed are not necessarily the order in which they areperformed.

In the foregoing specification, the concepts have been described withreference to specific embodiments. However, one of ordinary skill in theart appreciates that various modifications and changes can be madewithout departing from the scope of the invention as set forth in theclaims below. Accordingly, the specification and figures are to beregarded in an illustrative rather than a restrictive sense, and allsuch modifications are intended to be included within the scope ofinvention.

Benefits, other advantages, and solutions to problems have beendescribed above with regard to specific embodiments. However, thebenefits, advantages, solutions to problems, and any feature(s) that maycause any benefit, advantage, or solution to occur or become morepronounced are not to be construed as a critical, required, or essentialfeature of any or all the claims.

It is to be appreciated that certain features are, for clarity,described herein in the context of separate embodiments, may also beprovided in combination in a single embodiment. Conversely, variousfeatures that are, for brevity, described in the context of a singleembodiment, may also be provided separately or in any subcombination.Further, reference to values stated in ranges include each and everyvalue within that range.

What is claimed is:
 1. A process for making an OLED luminaire,comprising: providing a substrate having a first patterned electrodethereon; depositing a first liquid composition in a first pixellatedpattern to form a first deposited composition, the first liquidcomposition comprising a first electroluminescent material in a firstliquid medium, said first electroluminescent material having a firstemission color; depositing a second liquid composition in a secondpixellated pattern which is laterally spaced from the first pixellatedpattern to form a second deposited composition, the second liquidcomposition comprising a second electroluminescent material in a secondliquid medium, said second electroluminescent material having a secondemission color; depositing a third liquid composition in a thirdpixellated pattern which is laterally spaced from the first and secondpixellated patterns to form a third deposited composition, the thirdliquid composition comprising a third electroluminescent material in athird liquid medium, said third electroluminescent material having athird emission color; drying the deposited compositions to formpluralities of pixels; and forming a second electrode over all thepixels; wherein one of the emission colors is blue, one of the emissioncolors is green, and one of the emission colors is red-orange; whereinthe electroluminescent material with blue emission color has Formula I

wherein: R¹⁴, R¹⁵, R¹⁶ and R¹⁷ are the same or different and areselected from the group consisting of H, D, and alkyl, where R¹⁴ and R¹⁵groups or R¹⁶ and R¹⁷ groups may be joined together to form a 5- or6-membered aliphatic ring; R¹⁸ and R¹⁹ are the same or different and areselected from the group consisting of D, alkyl groups, silyl groups,m-phenyl, o-phenyl, p-phenyl, m-N-carbazolyl, and p-N-carbazolyl; R²⁰ isthe same or different at each occurrence and is selected from the groupconsisting of D, alkyl groups, silyl groups, phenyl, and biphenyl, ortwo adjacent R²⁰ groups can join together to form a naphthyl orfluorenyl group; a and b are the same or different and are an integerfrom 0-10; c and d are the same or different and are an integer from1-5; f, g, h, and i, are the same or different at each occurrence andare an integer from 0-4; and e and j are the same or different at eachoccurrence and are an integer from 0-5.
 2. The process of claim 1,wherein the electroluminescent material with blue emission color is atris-cyclometallated complex having the formula IrL₃ or abis-cyclometallated complex having the formula IrL₂Y, where Y is amonoanionic bidentate ligand and L has a formula selected from the groupconsisting of Formula L-1 through Formula L-12:

where R¹ through R⁸ are the same or different and are selected from thegroup consisting of H, D, electron-donating groups, andelectron-withdrawing groups, and R⁹ is H, D, or alkyl; * represents apoint of coordination with Ir.
 3. The process of claim 1, wherein therelative emission from the blue, green and red-orange colors, measuredin cd/m², is: blue emission=20-25%, green emission=47-52%, andred-orange emission=27-32%.
 4. The process of claim 1, wherein theelectroluminescent material with green emission color is atris-cyclometallated complex having the formula IrL₃ or abis-cyclometallated complex having the formula IrL₂Y, where Y is amonoanionic bidentate ligand and L has a formula selected from the groupconsisting of L-1, L-3 through L-7, and L-9 through L-17:

where R¹ through R⁸ are the same or different and are selected from thegroup consisting of H, D, electron-donating groups, andelectron-withdrawing groups, and R⁹ is H, D, or alkyl.
 5. The process ofclaim 1, wherein the electroluminescent material with red-orangeemission color is a tris-cyclometallated complex having the formula IrL₃or a bis-cyclometallated complex having the formula IrL₂Y, where Y is amonoanionic bidentate ligand and L has a formula selected from the groupconsisting of Formula L-18, L-19, L-20 and L-21:

where: R¹ through R⁶ and R²¹ through R³⁰ are the same or different andare selected from the group consisting of H, D, electron-donatinggroups, and electron-withdrawing groups; AND * represents a point ofcoordination with Ir.
 6. The process of claim 1, wherein any one or moreof the first, second, and third electroluminescent materials comprise ahost material having a formula selected from:An-L-AnandA-An-A wherein An is an anthracene moiety, L is a divalent connectinggroup, and A is the same or different at each occurrence and is anaromatic group.
 7. The process of claim 1, wherein one or more of thefirst, second, and third electroluminescent materials comprises a hostmaterial having the formula

where: Ar¹ to Ar⁴ are the same or different and are aryl; Q is selectedfrom the group consisting of multivalent aryl groups and

T is selected from the group consisting of (CR′)_(a), SiR₂, S, SO₂, PR,PO, PO₂, BR, and R; R is the same or different at each occurrence and isselected from the group consisting of alkyl, and aryl; R′ is the same ordifferent at each occurrence and is selected from the group consistingof H, D, and alkyl; a is an integer from 1-6; and m is an integer from0-6.
 8. The process of claim 1, wherein one or more of the first,second, and third electroluminescent materials comprise a host materialselected from the group consisting of:


9. The process of claim 1, wherein one or more of the first, second, andthird electroluminescent materials comprise a host material having theformula

where: R³¹ is the same or different and is selected from the groupconsisting of phenyl, naphthyl, naphthylphenyl, triphenylamino, andcarbazolylphenyl; R³² and R³³ are the same or different and are selectedfrom the group consisting of phenyl, biphenyl, naphthyl, naphthylphenyl,phenanthryl, triphenylamino, and carbazolylphenyl.
 10. The process ofclaim 2, wherein: R¹ is H, D, F, or alkyl; R² is H, D or alkyl; R³=H, D,F, alkyl, OR¹⁰, NR¹⁰ ₂; R⁴=H or D; R⁵=H, D or F; R⁶=H, D, CN, F, aryl,fluoroalkyl, or diaryloxophosphinyl; R⁷=H, D, F, alkyl, aryl, ordiaryloxophosphinyl; R⁸=H, D, CN, alkyl, fluoroalkyl; R⁹=H, D, or alkyl;and R¹⁰=alkyl, where adjacent R¹⁰ groups can be joined to form asaturated ring.
 11. The process of claim 2, wherein Y is selected fromthe group consisting of Y-1, Y-2 and Y-3

wherein: R¹¹ is the same or different at each occurrence and is selectedfrom the group consisting of alkyl and fluoroalkyl; R¹² is H, D or F;and R¹³ is the same or different at each occurrence and is selected fromthe group consisting of alkyl and fluoroalkyl.
 12. The process of claim2, wherein the relative emission from blue, green and red-orange colors,as measured in cd/m², is: blue emission=28-33%, green emission=32-37%,and red-orange emission=31-36%.
 13. The process of claim 4, wherein:R¹=H, D or F; R²=H, D, F, or alkyl; R³=H, D or diarylamino; R⁴=H, D orF; R⁵=H, D or alkyl, or R⁴ and R⁵ may be joined together to form a6-membered aromatic ring; R⁶=H, D, CN, F, aryl, fluoroalkoxy,N-carbazolyl, diphenyl-N-carbazolyl

R⁷=H, D, F, fluoroalkoxy, N-carbazolyl, or diphenyl-N-carbazolyl; R⁸=H,D or F; and R⁹=H, D, or alkyl, where the asterisk represents the pointof attachment.
 14. The process of claim 4, wherein Y is selected fromthe group consisting of Y-1, Y-2 and Y-3

wherein: R¹¹ is the same or different at each occurrence and is selectedfrom the group consisting of alkyl and fluoroalkyl; R¹² is H, D or F;and R¹³ is the same or different at each occurrence and is selected fromthe group consisting of alkyl and fluoroalkyl.
 15. The process of claim5, wherein: R¹ through R⁴ and R²¹ through R²⁶ are the same or differentand are H, D, alkyl, silyl, or alkoxy, or R¹ and R², R² and R³ or R³ andR⁴ in ligand L-18, or R²³ and R²⁴ or R²⁴ and R²⁵ in ligand L-19 andL-20, or R²³ and R²⁴, R²⁴ and R²⁵, or R²⁵ and R²⁶ can be joined togetherto form a hydrocarbon ring or hetero ring; R²⁷=H, D, alkyl, or silyl;R²⁸=H, D, alkyl, or silyl; R²⁹=H, D, alkyl, silyl, alkoxy, fluoroalkoxy,or aryl; and R³⁰=H, D, alkyl, or silyl.
 16. The process of claim 5,wherein Y is selected from the group consisting of Y-1, Y-2 and Y-3

wherein: R¹¹ is the same or different at each occurrence and is selectedfrom the group consisting of alkyl and fluoroalkyl; R¹² is H, D or F;and R¹³ is the same or different at each occurrence and is selected fromthe group consisting of alkyl and fluoroalkyl.
 17. The process of claim6, wherein the host material has the formula

where: A¹ and A² are the same or different at each occurrence and areselected from the group consisting of H, D, an aromatic group, an alkylgroup and an alkenyl group, or A may represent one or more fusedaromatic rings; p and q are the same or different and are an integerfrom 1-3.